[1,1,2,2‐(CO)4‐1,2‐μ‐(CO)‐4,11‐(SMe2)2‐closo‐1,2‐Co2B10H8] |
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Authors: | Michael G S Londesborough Jonathan Bould Josef Holub John D Kennedy Mark Thornton‐Pett Bohumil tíbr |
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Institution: | Michael G. S. Londesborough,Jonathan Bould,Josef Holub,John D. Kennedy,Mark Thornton‐Pett,Bohumil ?tíbr |
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Abstract: | The title compound, 1,1,2,2‐tetracarbonyl‐1,2‐μ‐carbonyl‐4,11‐dimethylsulfido‐closo‐1,2‐dicobaltadodecaborane, Co2(C4H20B10S2)(CO)5], has a closo 12‐vertex {1,2‐Co2B10H8} structure with SMe2 ligands at the exo‐4‐ and 11‐positions. The cluster displays close structural similarities to the SEt2 analogue. |
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