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[1,1,2,2‐(CO)4‐1,2‐μ‐(CO)‐4,11‐(SMe2)2‐closo‐1,2‐Co2B10H8]
Authors:Michael G S Londesborough  Jonathan Bould  Josef Holub  John D Kennedy  Mark Thornton‐Pett  Bohumil &#x;tíbr
Institution:Michael G. S. Londesborough,Jonathan Bould,Josef Holub,John D. Kennedy,Mark Thornton‐Pett,Bohumil ?tíbr
Abstract:The title compound, 1,1,2,2‐tetra­carbonyl‐1,2‐μ‐carbonyl‐4,11‐di­methyl­sulfido‐closo‐1,2‐dicobaltadodecaborane, Co2(C4H20B10S2)(CO)5], has a closo 12‐vertex {1,2‐Co2B10H8} structure with SMe2 ligands at the exo‐4‐ and 11‐positions. The cluster displays close structural similarities to the SEt2 analogue.
Keywords:
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