{2,2′‐[(R,R)‐Cyclohexane‐1,2‐diylbis(nitrilomethylidyne)]bis[6‐tert‐butyl‐4‐(triphenylphosphoniomethyl)phenolato]‐O,N,N′,O′}copper(II) dichloride hexakis(deuterochloroform) solvate |
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Authors: | Aarne Pajunen Ilpo Mutikainen Anssi Haikarainen Jussi Sipil Pekka Pietikinen |
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Institution: | Aarne Pajunen,Ilpo Mutikainen,Anssi Haikarainen,Jussi Sipilä,Pekka Pietikäinen |
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Abstract: | The title compound, Cu(C66H68N2O2P2)]Cl2·6CDCl3, consists of complex cations, chloride ions and deuterochloroform solvate molecules. The complex cation crystallizes in two different conformations. In both cases, CuII ions lie on twofold axes and the geometry around them is slightly distorted square planar. The dihedral angles between the N/Cu/N and O/Cu/O planes are 5.6 (9) and 3.9 (10)° for molecules A and B, respectively. |
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