New phosphorus-containing metal phthalocyanine complexes. Synthesis and spectral and electrochemical studies |
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| Authors: | A. V. Ivanov K. V. Kabanova M. O. Breusova I. V. Zhukov L. G. Tomilova N. S. Zefirov |
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| Affiliation: | (1) Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyi proezd, 142432 Chernogolovka, Moscow Region, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992 Moscow, Russian Federation |
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| Abstract: | ![]()
Hitherto unknown phosphorus-containing 4,5-bis(diethoxyphosphorylmethyl)- and 4-methyl-5-diethoxyphosphorylmethylphthalonitriles were synthesized starting from o-xylene. Their tetramerization afforded free phthalocyanine ligands and their complexes with Zn, Ni, Co, and a number of rare-earth metals. The spectral and electrochemical properties of the phthalocyanines synthesized were studied. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1634–1638, August, 2008. |
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| Keywords: | phthalocyanines phthalonitrile Arbuzov reaction |
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