Study of [Fe(pyim)3] complexes: dynamic spin equilibrium on encapsulation in zeolite Y |
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Authors: | R Vijayalakshmi SK Kulshreshtha |
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Institution: | a Novel Materials and Structural Chemistry Division, Bhabha Atomic Research Centre, Trombay74, Mumbai 400 085, India b Solid State Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085, India |
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Abstract: | Tris complex of FeII2(2′-pyridyl)imidazole has been encapsulated in the supercages of zeolite Y and characterized by using powder XRD, FTIR, Mössbauer spectroscopy, variable temperature magnetization and MAS NMR techniques and results have been compared with those obtained for this complex with ClO4− and SO42− as anions. At room temperature, the Fe(pyim)3](ClO4)2 complex exhibited low spin state, while FeII(pyim)3]SO4 exhibited the existence of both low and high spin states. The encapsulated FeII(pyim)3]2+ complex exhibited a broad quadrupole doublet characterized by isomer shift, δ=+0.55 mm/s and quadrupole splitting ΔEq=1.26 mm/s. The magnetization measurements carried out for the encapsulated FeII(pyim)3]2+ complex showed a systematic decrease in its values with decreasing temperature down to 75 K with no indication of thermal hysteresis effects. These results suggest the existence of a dynamic spin state equilibrium between the high and low spin states for the encapsulated FeII(pyim)3]2+ complex with time constant comparable to the characteristic Mössbauer time scale of 57Fe nuclei. |
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Keywords: | Spin State equilibrium FeII complex Zeolite Magnetization Mö ssbauer and NMR spectra |
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