A Selective Conversion of Benzylic Alcohols to the Corresponding Carbonyl Compounds by Means of an Ag(III) Complex |
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| Authors: | Zorica Bugarcěi? Slobodan Novokmet Zěeljko Seni? and Zěivadin Bugarcěi? |
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| Institution: | (1) School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK;(2) SiGNa Chemistry, Inc., 530 East 76th Street, Suite 9E, New York, NY 10021, USA; |
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| Abstract: | Carbonyl compounds of the type XPhCOR (R = H, Me, Ph; X = H, Me, Cl, Br) are prepared in high yields by reaction of the corresponding benzylic alcohols XPhCHOHR with KNa4 Ag(HIO6)2]×12H2O in alkaline solution. This method allows the selective oxidation of benzylic alcohols in compounds containing other types of alcoholic functional groups. |
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