| Controlled Radical Photopolymerization of n-Butyl Methacrylate in Bluk Mediated by HTEMPO |
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| 引用本文： | Xiao Xuan LIU Mei HAN Lun Yong DUAN Guang Guo WU. Controlled Radical Photopolymerization of n-Butyl Methacrylate in Bluk Mediated by HTEMPO[J]. 中国化学快报, 2006, 17(8): 1109-1112 |
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| 作者姓名： | Xiao Xuan LIU Mei HAN Lun Yong DUAN Guang Guo WU |
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| 作者单位： | Xiao Xuan LIU，Mei HAN，Lun Yong DUAN，Guang Guo WU Department of Chemistry，College of Science，Shantou University，Shantou 515063 |
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| 基金项目： | 国家自然科学基金;广东省自然科学基金 |
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| 摘 要： | Recently, controlled free-radical polymerization (CRP) has been a technique for the preparation of polymers of tailored architectures using experimentally simple techniques1. The CRP methods were nitroxide-mediated free radical polymerization (NMP), atom …
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| 关 键 词： | 光聚作用 硝基氧 n-丁基异丁烯酸酯 HTEMPO |
| 收稿时间： | 2006-01-06 |
Controlled Radical Photopolymerization of n-Butyl Methacrylate in Bluk Mediated by HTEMPO |
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| Xiao Xuan LIU,Mei HAN,Lun Yong DUAN,Guang Guo WU. Controlled Radical Photopolymerization of n-Butyl Methacrylate in Bluk Mediated by HTEMPO[J]. Chinese Chemical Letters, 2006, 17(8): 1109-1112 |
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| Authors: | Xiao Xuan LIU Mei HAN Lun Yong DUAN Guang Guo WU |
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| Abstract: | Controlled radical photopolymerization of n-butyl methacrylate(n-BMA) mediated by 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxy(HTEMPO) was carried out in bulk at ambient temperature. It was found that obtained n-BMA homopolymers exhibited narrow polydispersities of around 1.4, which was characterized by GPC. Plots of number-average molecular weight vs. conversion and Ln([M0]/[M]) vs. time were liner respectively, indicating that was a controlled photopolymerization. |
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| Keywords: | Photopolymerization nitroxide n-butyl methacrylate HTEMPO. |
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