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Isothermal vapor-liquid equilibria for methanol and 2,3-dimethyl-2-butene at 343.15 K, 353.15 K, 363.15 K, 373.15 K
Authors:Chuanzhuang FengJilian Dong  Yonghong Li
Institution:a Key Laboratory for Green Chemical Technology of State Education Ministry, Tianjin 300072, PR China
b National Engineering Research Center for Distillation Technology, Tianjin 300072, PR China
Abstract:Isothermal vapor-liquid equilibrium (VLE) data were measured for the binary system methanol and 2,3-dimethyl-2-butene at 343.15 K, 353.15 K, 363.15 K, 373.15 K, respectively. The measurements were carried out in a novel recirculation equilibrium equipment. Three activity coefficient models including Wilson, NRTL and UNIQUAC, as well as the Soave-Redlich-Kwong equation of state were used to correlate the experimental data. The correlation results showed that a good consistency between the experimental data and the Wilson model can be achieved.
Keywords:Vapor-liquid equilibrium  Methanol  2  3-Dimethyl-2-butene
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