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Synthesis, optical and electroanalytical characterizations of a thiacalix[4](N-phenylazacrown-5)ether-BODIPY ionophore |
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| Authors: | Viktor Csokai,Diem Lan Ha Mai,Olí via Varga,Klá ra Tó th,Mikló s Kubinyi,Alajos Grü n |
| Affiliation: | a Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, H-1521 Budapest, Hungary b Research Group of Technical Analytical Chemistry of Hungarian Academy of Sciences, Budapest University of Technology and Economics, H-1521 Budapest, Hungary c Department of Inorganic Chemistry, Budapest University of Technology and Economics, H-1521 Budapest, Hungary d Department of Analytical Chemistry, Budapest University of Technology and Economics, H-1521 Budapest, Hungary e Department of Physical Chemistry, Budapest University of Technology and Economics, H-1521 Budapest, Hungary f Department of Materials Science, Budapest University of Technology and Economics, H-1521 Budapest, Hungary g Chemical Research Center, Hungarian Academy of Sciences, PO Box 17, H-1525 Budapest, Hungary |
| Abstract: | Novel fluorogenic 1,3-alt thiacalix[4](N-phenylazacrown-5)ether ionophore has been synthesized by conjugation of the N-phenyl group with borondipyrromethene (BODIPY) fluorophore moiety. The ionophore exhibits pronounced off-on type fluorescent responses to some transition metal ions, in particular to Cu2+. In a PVC membrane electrode, distinct Ag+ selectivity was observed in potentiometric transduction. |
| Keywords: | Thiacalix[4]crowns Complexation BODIPY Fluorescence Ion selectivity ISE |
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