| Sharpless四唑合成中捕获双四唑锌配合物 |
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| 引用本文： | 王立中,王锡森,李咏华,白志平,熊仁根,熊明,李国武.Sharpless四唑合成中捕获双四唑锌配合物[J].无机化学学报,2002,18(12):1191-1194. |
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| 作者姓名： | 王立中 王锡森 李咏华 白志平 熊仁根 熊明 李国武 |
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| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093
2. 中国地质大学地球科学实验室,北京,100083 |
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| 基金项目： | 国家重点基础研究发展规划资助项目(G2000077500)，国家自然科学基金资助项目，教育部优秀青年教师资助计划项目。 |
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| 摘 要： | The reaction of malononitrile with ZnCl2 and NaN3 in the presence of 2,2′-bipyridine and water affords the first bis(tetrazole) Zn-complex intermediate, mono(2,2′-bipyridine)bis(tetrazolyl)methane aqua zinc(Ⅱ), Zn(2,2′-bpy)(BTZ)(H2O)]·(H2O)2 (1) which gives a clue for Demko-Sharpless′ tetrazole synthesis. Crystal data for 1: C13H18N10O4Zn, Mr=443.74, monoclinic, space group P21/c, a=12.5705(18), b=16.078(2), c=9.1921(13)?, β=95.010(3)°, V=1850.7(5)?3, Z=4. CCDC: 197788.
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| 关 键 词： | 双四唑 水热合成 锌配位聚合物 |
Trapping of Zn-Complex with Bis(tetrazole) Ligand during the Demko-Sharpless' Tetrazole Synthesis |
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| WANG Li-Zhong,WANG Xi-Sen,LI Yong-Hu,BAI Zhi-Ping,XIONG Ren-Gen,XIONG Ming and LI Guo-Wu.Trapping of Zn-Complex with Bis(tetrazole) Ligand during the Demko-Sharpless'''' Tetrazole Synthesis[J].Chinese Journal of Inorganic Chemistry,2002,18(12):1191-1194. |
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| Authors: | WANG Li-Zhong WANG Xi-Sen LI Yong-Hu BAI Zhi-Ping XIONG Ren-Gen XIONG Ming and LI Guo-Wu |
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| Institution: | Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University,Nanjing 210093,Geoscience Laboratories, China University of Geosciences, Beijing 100083 and Geoscience Laboratories, China University of Geosciences, Beijing 100083 |
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| Abstract: | The reaction of malononitrile with ZnCl2 and NaN3 in the presence of 2, 2'-bipyridine and water affords the firstbis(tetrazole) Zn-complex intermediate, mono(2, 2'-bipyridine) bis(tetrazolyl) methane aqua zinc (Ⅱ), Zn(2, 2'-bpy) (BTZ) (H2O) ] @ (H2O)2 (1) which gives a clue for Demko-Sharpless' tetrazole synthesis. Crystal data for 1:C13H18N10O4Zn, Mr =443.74, monoclinic, space group P21/c, a= 12. 5705(18), b = 16. 078(2), c =9. 1921(13)A, β=95.010(3)°, V=1850.7(5)A3, Z=4. CCDC: 197788. |
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| Keywords: | bis-tetrazole hydrothermal synthesis zinc coordination polymer |
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