| 多硫二硫烯铜配合物(n-Bu4N)[Cu(cddt)2]和(Ph4P)[Cu(cddt)2]的合成、表征及其结构 |
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| 引用本文： | 纪勇,左景林,涂超,蔡晨新,李一志,张建强.多硫二硫烯铜配合物(n-Bu4N)[Cu(cddt)2]和(Ph4P)[Cu(cddt)2]的合成、表征及其结构[J].无机化学学报,2002,18(11):1123-1126. |
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| 作者姓名： | 纪勇 左景林 涂超 蔡晨新 李一志 张建强 |
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| 作者单位： | 南京大学配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 海外杰出青年基金资助项目(No.29929001)。 |
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| 摘 要： | Two copper complexes with a new multi-sulfur 1,2-dithiolene ligand, CCu(cddt)2] (C=tetrabutylammoni-um, n-Bu4N+; tetraphenylphosphonium, Ph4P+; cddt = 4a, 6, 7, 7a-5H-cyclopentab]-1,4-dithiin-2,3 dithi-olate) have been synthesized and characterized by electrochemical studies, IR, EA, etc. The structure of (Ph4P)Cu(cddt)2] was determined by single crystal X-ray analysis. The complex was crystallized in the triclinic, space group P1 with the cell dimensions a=10.460(2)?, b=13.000(3)?,c=16.270(3)?, α=86.68(3)°,β= 71.92(3)°,γ=66.66(3)° and Z=2. R1=0.0548, wR2=0.1358 for 6786 independent reflections. The four S atoms surround the Cu atom CuS4] core is a square-planar environment.
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| 关 键 词： | 晶体结构 循环伏安 多硫二硫烯铜配合物 |
Synthesis and Characterization of (n-Bu4N)[Cu(cddt)2] and (Ph4P)[Cu(cddt)2] (cddt=4a,6,7,7a-5H-cyclopenta[b]-1,4-dithiin-2,3-dithiolate); X-ray Crystal Structure of (Ph4P)[Cu(cddt)2] |
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| JI Yong,ZUO Jing-Lin,TU Chao,CAI Chen-Xin,LI Yi-Zhi and ZHANG Jian-Qiang.Synthesis and Characterization of (n-Bu4N)[Cu(cddt)2] and (Ph4P)[Cu(cddt)2] (cddt=4a,6,7,7a-5H-cyclopenta[b]-1,4-dithiin-2,3-dithiolate); X-ray Crystal Structure of (Ph4P)[Cu(cddt)2][J].Chinese Journal of Inorganic Chemistry,2002,18(11):1123-1126. |
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| Authors: | JI Yong ZUO Jing-Lin TU Chao CAI Chen-Xin LI Yi-Zhi and ZHANG Jian-Qiang |
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| Institution: | State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | Two copper complexes with a new multi-sulfur 1, 2-dithiolene ligand, CCu(cddt)2] (C = tetrabutylammoni-um, n-Bu4N+; tetraphenylphosphonium, Ph4P+; cddt = 4a, 6, 7, 7a-5H cyclopentab]-1, 4-dithiin-2, 3 dithi-olate) have been synthesized and characterized by electrochemical studies, IR, EA, etc. The structure of (Ph4P)Cu(cddt)2] was determined by single crystal X-ray analysis. The complex was crystallized in the triclinic, spacegroup P-1 with the cell dimensions a = 10. 460(2) A, b = 13.000(3) A, c = 16. 270(3) A, α =86. 68(3)°, β=71.92 (3)°, γ = 66.66 (3)° and Z = 2. R1 = 0. 0548, w R2 = 0. 1358 for 6786 independent reflections. The four Satoms surround the Cu atom CuS4] core is a square-planar environment. |
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| Keywords: | crystal structure cyclic voltammetry copper bisdithiolene |
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