Oxidative Transformations of Phenylacetylene on a Manganese(IV) Oxide Adsorbent-Catalyst |
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Authors: | Kapran A. Yu. |
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Affiliation: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03039 Kyiv, Ukraine |
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Abstract: | It is shown by IR spectroscopy and thermally programmed surface reactions that the complete oxidation of phenylacetylene on hydrated manganese dioxide in an adsorption catalytic regime occurs via dissociation of the C C bond (during chemisorption) with the formation of formate and benzoate on the surface. |
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