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Oxidative Transformations of Phenylacetylene on a Manganese(IV) Oxide Adsorbent-Catalyst
Authors:Kapran  A. Yu.
Affiliation:(1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03039 Kyiv, Ukraine
Abstract:It is shown by IR spectroscopy and thermally programmed surface reactions that the complete oxidation of phenylacetylene on hydrated manganese dioxide in an adsorption catalytic regime occurs via dissociation of the CequivC bond (during chemisorption) with the formation of formate and benzoate on the surface.
Keywords:
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