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Effect of La2O3/γ—Al2O3 Catalyst on the Activation of CH4 and CO2 to C2 Hydrocarbons under Non—equilibrium Plasma
引用本文:XiuLingZHANG WeiMinGONG 等. Effect of La2O3/γ—Al2O3 Catalyst on the Activation of CH4 and CO2 to C2 Hydrocarbons under Non—equilibrium Plasma[J]. 中国化学快报, 2002, 13(2): 175-176
作者姓名:XiuLingZHANG WeiMinGONG 等
作者单位:[1]CenterofAnalysis,DalianInstituteofLightIndustry,Dalian116031 [2]PlasmaandChemistryLaboratory,DalianUniversityofTechnology,Dalian116012
摘    要:In the reaction of methane and carbon dioxide to C2 hydrocabons under non-equilibrium plasma, methane conversion was decreased,but selectivity of C2 hydroxarbons was increased when using La2O3/γ-Al2O3 as catalyst. So the yield of C2 hydrocarbons was higher than using plasma alone. The synergism of La2O3/γ-Al2O3 and plasma gave methane conversion of 24.9% and C2 yield of 18.1%. The distribution of C2 hydrocarbons changed when Pd-La2O3/γ-Al2O3 was used as catalyst,the major C2 product was ethylene.

关 键 词:γ-三氧化二铝 催化剂 甲烷 二氧化碳 三氧化二镧 不平衡等离子体 C2烃 C2碳氢化合物

Effect of La2O3/γ-Al2O3 Catalyst on the Activation of CH4 and CO2 to C2 Hydrocarbons under Non-equilibrium Plasma
Xiu Ling ZHANG,Wei Min GONG,Bin DAI,Chang Hou LIU. Effect of La2O3/γ-Al2O3 Catalyst on the Activation of CH4 and CO2 to C2 Hydrocarbons under Non-equilibrium Plasma[J]. Chinese Chemical Letters, 2002, 13(2): 175-176
Authors:Xiu Ling ZHANG  Wei Min GONG  Bin DAI  Chang Hou LIU
Abstract:In the reaction of methane and carbon dioxide to C2 hydrocarbons under non-equilibrium plasma, methane conversion was decreased, but selectivity of C2 hydrocarbons was increased when using La2O3/γ-Al2O3 as catalyst. So the yield of C2 hydrocarbons was higher than using plasma alone. The synergism of La2O3/γ-Al2O3 and plasma gave methane conversion of 24.9% and C2 yield of 18.1%. The distribution of C2 hydrocarbons changed when Pd- La2O3/γ-Al2O3 was used as catalyst, the major C2 product was ethylene.
Keywords:Non-equilibrium plasma  catalyst  methane  carbon dioxide
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