Coordination complexes of 2,6-diarylpyrazines with copper(II) acetate期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Coordination complexes of 2,6-diarylpyrazines with copper(II) acetate

Authors:	Nate?Schultheiss,Douglas?R.?Powell,Eric?Bosch author-information" > author-information__contact u-icon-before" > mailto:erbf@smsu.edu" title=" erbf@smsu.edu" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author

Affiliation:	(1) Department of Chemistry, Southwest Missouri State University, 901 South National Avenue, Springfield, Missouri;(2) Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas

Abstract:	The coordination chemistry of a series of 2,6- and 2,3-diarylpyrazines with copper(II) acetate is reported. The 2:2 coordination complexes formed between two 2,6-diarylpyrazines and copper(II) acetate are characterized by X-ray crystallography. The structure (2,6-bis(3,5-dimethylphenyl)pyrazine)copper(II) acetate acetonitrile solvate, (C₄₈H₅₂Cu₂N₄O₈) (C₂H₃N) is triclinic, P 1, with a = 7.9685(10), b = 13.1893(16), c = 13.8267(17) Å, = 107.585(3)°, = 103.921(3)° and = 96.759(3)°. The structure of (2-(2,6-dimethylphenyl)-6-(3,5-dimethylphenyl)pyrazine)copper(II) acetate, C₄₈H₅₂Cu₂N₄O₈, is monoclinic, P2₁/c, with a = 8.2196(7), b = 12.5174(11), c = 21.7325(19) Å and = 96.201(2)°.

Keywords:	2,6-Diarylpyrazine 2,3-diarylpyrazine crystal structure coordination complex copper(II) acetate
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