Critical temperatures and pressures of linear alk-1-enes with 13 to 20 carbon atoms using the pulse-heating technique |
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Institution: | Institute of Thermal Physics, Ural Branch of the Russian Academy of Sciences, GSP-828, Pervomaiskaya St. 91, 620219 Ekaterinburg, Russian Federation |
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Abstract: | The paper presents experimental critical temperatures and critical pressures of thermally unstable alk-1-enes CnH2n with a number of carbon atoms n=13–20. The method of pulse heating of a wire probe placed in the liquid under investigation has been used. Equations for correlation of the critical temperatures and pressures of alk-1-enes with a number of carbon atoms in a molecule have been obtained. The acentric factors of alk-1-enes have been calculated. |
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