Development of a Modified Bromley's Methodology for the estimation of ionic media effects on solution equilibria: Part 3. Application to the construction of thermodynamic models |
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| Institution: | 1. School of Geoscience and Surveying Engineering, China University of Mining & Technology, Beijing 100083, China;2. The Key Laboratory of Solid Waste Treatment and Resource, Ministry of Education, Southwest University of Science and Technology, 621010 Mianyang, China |
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| Abstract: | The development of the Modified Bromley's Methodology (MBM) is extended for the estimation of the activity coefficients of individual species in aqueous solution at 25°C in single and mixed ionic media. The estimation is compared with literature data of activity coefficients of mixtures of electrolytes in water and applied to (a) the prediction of the ionic product of water in aqueous solutions containing different salts which are commonly used as background electrolytes (NaCl, KNO3 and NaClO4) and (b) the equilibrium constants of the Cr(VI)–H2O system. |
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