Mathematical modeling of photoisomerization with intramolecular proton transfer |
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Authors: | V A Morozov |
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Institution: | 1.Zelinskii Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | A system of equations describing time changes in the matrix elements of the density operator of a seven-level model of a molecule
interacting with a light pulse taking into account spontaneous (including collective) decays of molecule excited states is
suggested. Model parameters were selected to allow us to perform modeling of the photoisomerization of a molecule with two
isomeric states with different stable proton positions on an intramolecular H-bond by numerically solving the suggested system
of equations for density operator matrix elements. An analysis of the characteristic time dependences of the population of
states of the model under consideration showed that proton phototransfer in the collective decay of various isomeric states
of a molecule in an excited electronic state can be one of effective mechanisms of the photoisomerization of molecules whose
structure is described by the model. |
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Keywords: | |
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