Fluorous phase transfer catalysts: From onium salts to crown ethers |
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| Authors: | Gianluca Pozzi Silvio Quici |
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| Institution: | a CNR-Istituto di Scienze e Tecnologie Molecolari, via Golgi 19, 20133 Milano, Italy
b Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA |
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| Abstract: | Fluorous quaternary ammonium and phosphonium salts, as well as fluorous macrocyclic ligands, such as crown and aza-crown ethers, have been gradually emerging as viable alternatives to classical phase transfer catalysts. The major results thus far obtained in this burgeoning field will be the focus of this review. |
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| Keywords: | Ammonium salts Fluorinated ligands Multiphase catalysis Phosphonium salts Perfluorocarbons Waste minimization |
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