| SYNTHESIS AND CRYSTAL STRUCTURE OF MoS4Cu4I2（Py）6 |
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| 引用本文： | 李纪国,陈尼勤,等. SYNTHESIS AND CRYSTAL STRUCTURE OF MoS4Cu4I2（Py）6[J]. 结构化学, 1992, 11(5): 351-353 |
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| 作者姓名： | 李纪国 陈尼勤 等 |
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| 摘 要： | <正> C30H30Cu4I2S4MoN6,Mr=1206, orthorhombic, Fdd2, a = 22. 511(4), b= 22.946(4), c=30. 742(6)(?), Z = 16, Dc = 2. 019g/cm3, V = 15879.4 (?)3, μ = 41. 884cm-1, F (000) = 9280. The final R factor is 0. 0279 for 1884 observed reflections with I>3σ(I). Crystal structure analysis shows that the MoS4Cu4 aggregate is formed, each the four copper atoms is linked with two S atoms of the te-trahedral MoS42- core. The average distance between Mo and Cu atoms is 2. 678(?).
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| 关 键 词： | 合成 晶体 结构 吡啶 钼 铜 金属配合物 |
SYNTHESIS AND CRYSTAL STRUCTURE OF MoS_4Cu_4I_2(Py)_6 |
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| Affiliation: | [1]Coordinationchemistryinstitute,NanjingUniversity,N [2]Coordinationchemistryinstitut,NanjingUniversity,N |
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| Abstract: | C30H30Cu4I2S4MoN6,Mr=1206, orthorhombic, Fdd2, a = 22. 511(4), b= 22.946(4), c=30. 742(6)(?), Z = 16, Dc = 2. 019g/cm3, V = 15879.4 (?)3, μ = 41. 884cm-1, F (000) = 9280. The final R factor is 0. 0279 for 1884 observed reflections with I>3σ(I). Crystal structure analysis shows that the MoS4Cu4 aggregate is formed, each the four copper atoms is linked with two S atoms of the te-trahedral MoS42- core. The average distance between Mo and Cu atoms is 2. 678(?). |
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