| 一维链状锰配位聚合物[Mn(1,5-nds)(Him)_4]_n的合成、晶体结构及热稳定性研究(英文) |
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| 引用本文： | 钱保华,马卫兴,陆路德,杨绪杰,汪 信. 一维链状锰配位聚合物[Mn(1,5-nds)(Him)_4]_n的合成、晶体结构及热稳定性研究(英文)[J]. 无机化学学报, 2010, 26(7): 1289-1293 |
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| 作者姓名： | 钱保华 马卫兴 陆路德 杨绪杰 汪 信 |
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| 作者单位： | 1. 淮海工学院化学工程学院,连云港,222005:
2. 南京理工大学材料化学实验室,南京,210094 |
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| 基金项目： | 江苏省高校科研成果产业化推进项目 |
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| 摘 要： | The synthesis,structural characterization and thermal behavior of a novel one-dimensional manganese (Ⅱ) complex of formula [Mn(1,5-nds)(Him)4]n [1,5-nds=naphthalene-1,5-disulfonate,Him=imidazole] is reported.The complex crystallizes in the triclinic system,space group P1,with a=0.835 42(13) nm,b=0.983 45(18) nm,c= 0.987 42(19) nm,α=60.523 0(10)°,β=97.748(2)°,γ=87.189(2)° and Z=2.The 1,5-nds ligand assumes the μ2 coordination mode and interlinks Mn(Ⅱ) ions into infinite one-dimensional chain structure along [111] direction,with the adjacent Mn…Mn distance being 1.144 99(12) nm.The chains are assembled into a three-dimensional supramolecular architecture via hydrogen bonds and C-H…π interactions.IR spectra and thermal analysis data are in agreement with the crystal structure.
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| 关 键 词： | 锰配合物； 配位聚合物； 1，5-萘二磺酸根； 晶体结构； 热稳定性 |
Synthesis, Crystal Structure and Thermal Stability of 1D Manganese Coordination Polymer [Mn(1,5-nds)(Him)4]n |
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| QIAN Bao-Hu,MA Wei-Xing,LU Lu-De,YANG Xu-Jie and WANG Xin. Synthesis, Crystal Structure and Thermal Stability of 1D Manganese Coordination Polymer [Mn(1,5-nds)(Him)4]n[J]. Chinese Journal of Inorganic Chemistry, 2010, 26(7): 1289-1293 |
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| Authors: | QIAN Bao-Hu MA Wei-Xing LU Lu-De YANG Xu-Jie WANG Xin |
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| Affiliation: | School of Chemical Technology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005,School of Chemical Technology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 and Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 |
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| Abstract: | The synthesis, structural characterization and thermal behavior of a novel one-dimensional manganese (II) complex of formula [Mn(1,5-nds)(Him)4]n [1,5-nds=naphthalene-1,5-disulfonate, Him=imidazole] is reported. The complex crystallizes in the triclinic system, space group P1, with a=0.83542(13) nm, b=0.983 45(18) nm, c= 0.987 42(19) nm, α=60.523 0(10)°, β=97.748(2)°, γ=87.189(2)° and Z=2. The 1,5-nds ligand assumes the μ2 coordination mode and interlinks Mn(II) ions into infinite one-dimensional chain structure along [111] direction, with the adjacent Mn…Mn distance being 1.14499(12) nm. The chains are assembled into a three-dimensional supramolecular architecture via hydrogen bonds and C-H… π interactions. IR spectra and thermal analysis data are in agreement with the crystal structure. |
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| Keywords: | coordination polymer 1,5-naphthalenedisulfonate crystal structure thermal stability |
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