Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer |
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| Authors: | Rufus Smits Yelena Goncharenko Baiba Skrivele Brigita Vigante Aiva Plotniece |
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| Institution: | a Latvian Institute of Organic Synthesis, Aizkraukles str. 21, Riga LV-1006, Latvia
b Faculty of Physics and Mathematics, University of Latvia, Zellu str. 8, Riga LV-1002, Latvia |
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| Abstract: | The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1H)-pyridone-5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS). |
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| Keywords: | Fluorous cationic amphiphiles Self-assembly 3 4-Dihydropyridone |
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