| 钯催化芳卤与亚磷酸二烷酯的相转移偶联反应 |
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| 引用本文： | 黄志真. 钯催化芳卤与亚磷酸二烷酯的相转移偶联反应[J]. 浙江大学学报(理学版), 1998, 25(3): 59-61 |
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| 作者姓名： | 黄志真 |
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| 作者单位： | 杭州大学化学系 |
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| 摘 要： | 在钯、碳酸钾及相转移催化剂的存在下, 芳卤与亚磷酸二烷酯在间二甲苯中共热可顺利发生交叉偶联反应, 提供了芳基膦酸二烷酯的简便合成法.
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| 关 键 词： | 钯催化 偶联反应 相转移反应 芳基膦酸二烷酯 合成 |
Palladium Catalyzed Coupling Reaction of Aryl Halides with Dialkyl Phosphiteds under PTC |
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| Huang Zhizhen Huang Xian. Palladium Catalyzed Coupling Reaction of Aryl Halides with Dialkyl Phosphiteds under PTC[J]. Journal of Zhejiang University(Sciences Edition), 1998, 25(3): 59-61 |
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| Authors: | Huang Zhizhen Huang Xian |
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| Affiliation: | (Dept .of Chem ., Hang zhou Unvier , Hang zhou 310028) |
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| Abstract: | In the presence of Pd(PPh 3) 4 and methyltrioctyl ammonium chloride, aryl halides can undergo crosscoupling reaction with dialkyl phosphites to support a convenient method for the synthesis of dialkyl arylphosphonates. |
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| Keywords: | palladium catalysis coupling reaction phase transfer conditions dialkyl aryphosphonates synthesis |
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