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Copper-free, recoverable dendritic Pd catalysts for the Sonogashira reaction
Authors:Heuzé Karine  Méry Denise  Gauss Dominik  Astruc Didier
Institution:Groupe Nanosciences Moléculaires et Catalyse, LCOO, UMR CNRS No 5802, Université de Bordeaux 1, 351 cours de la libération, 33405 Talence Cedex, France. k.heuze@lcoo.u-bordeaux1.fr
Abstract:Three generations of bidentate phosphinated Pd(II) dendrimers are efficient catalysts in the absence of copper co-catalyst for the Sonogashira reaction and are, with two cyclohexyl substituents on the phosphorus atoms, recovered by precipitation and re-used.
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