Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C-B bond formation with aryl halides |
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| Authors: | Euzenat Lisenn Horhant David Ribourdouille Yann Duriez Christophe Alcaraz Gilles Vaultier Michel |
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| Institution: | S. E. S. O. UMR-CNRS 6510, Université de Rennes1-Beaulieu, F-35042, Rennes, France. |
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| Abstract: | Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino)boranes R1R2N-BH2 (R1 and R2 = alkyl) that are new and efficient boron-sources in the Pd0 catalyzed borylation reaction affording monomeric aryl(dialkylamino)boranes R1R2N-BHR3 (R3 = aryl). |
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