| Synthesis and Crystal Structure of （SiCl3）2Fe（CO）4 |
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| 引用本文： | 陶弦,冯猛,张义颖,李月琴,王宁,沈应中.Synthesis and Crystal Structure of （SiCl3）2Fe（CO）4[J].结构化学,2009,28(3):287-290. |
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| 作者姓名： | 陶弦 冯猛 张义颖 李月琴 王宁 沈应中 |
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| 作者单位： | Applied Chemistry Department, School of Material Science & Engineering,Nanjing University of Aeronautics & Astronautics, Nanjing 21 O016, China
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| 基金项目： | 国家高技术研究发展计划(863计划)，江苏省自然科学基金，Foundation for Liu Da Ken Cai of Jiangsu Province，State Postdoctoral Foundation of China，the Postdoctoral Foundation of Jiangsu Province |
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| 摘 要： | The compound （SiCl3）2Fe（CO）4 was synthesized and structurally characterized by X-ray single-crystal diffraction. It crystallizes in monoclinic, space group P2 1/n with α = 8.287（2）, b = 9.829（2）, c = 9.042（2） A, β = 96.19（3）°, V= 732.2（3） A^3, C4Cl6FeO4Si2, Mr = 436.77, Z = 2, Dc = 1.981 g/cm^3, F（000） = 424, μ（MoKα） = 2.282 mm^-1, the final R = 0.048 and wR = 0.164 for 1109 observed reflections （I 〉 2σ（I））. The crystal structure of （SiCl3）2Fe（CO）4 reveals that the Si（l）- Fe-Si（l）^a sequence is linear and perpendicular to the Fe（CO）4 cross-shaped plane.
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| 关 键 词： | 晶体结构 主任 合成 结构特征 单晶衍射 单斜晶系 偏差因子 化合物 |
Synthesis and Crystal Structure of (SiCl_3)_2Fe(CO)_4 |
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| TAO Xian,FENG Meng,ZHANG Yi-Ying,LI Yue-Qin,WANG Ning,SHEN Ying-Zhong.Synthesis and Crystal Structure of (SiCl_3)_2Fe(CO)_4[J].Chinese Journal of Structural Chemistry,2009,28(3):287-290. |
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| Authors: | TAO Xian FENG Meng ZHANG Yi-Ying LI Yue-Qin WANG Ning SHEN Ying-Zhong |
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| Institution: | Applied Chemistry Department, School of Material Science & Engineering,Nanjing University of Aeronautics & Astronautics, Nanjing 21 O016, China |
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| Abstract: | The compound (SiCI3)2Fe(CO)4 was synthesized and structurally characterized by X-ray single-crystal diffraction. It crystallizes in monoclinic, space group P21/n with a = 8.287(2), b = 9.829(2), c = 9.042(2) A, β = 96.19(3)°, V = 732.2(3) A3, C4Cl16FeO4Si2, Mr = 436.77, Z = 2, Dc=1.981 g/cm3, F(000) = 424, μ(MoKa) = 2.282 mm-1, the final R = 0.048 and wR = 0.164 for 1109 observed reflections (I > 2σ(I)). The crystal structure of (SiCl3)2Fe(CO)4 reveals that the Si(1)-Fe-Si(1)a sequence is linear and perpendicular to the Fe(CO)4 cross-shaped plane. |
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| Keywords: | (SiCl3)2Fe(CO)4 single precursor crystal structure |
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