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Synthesis of 2-Substituted Benzimidazoles, Benzoxazoles, and Benzothiazoles from Arylsulfonyl(thio)propionitriles
Authors:Yu. A. Moskvichev  N. P. Gerasimova  A. N. Pashinin  P. V. Korikov  N. A. Nozhnin  E. M. Alov  O. S. Kozlova
Affiliation:(1) Yaroslavl State Technical University, Yaroslavl, 150023, Russia
Abstract:
The reaction of nitriles and of methyl imino ester hydrochlorides of arylsulfonyl(thio)propionic acids with o-phenylenediamine, o-aminophenol, and o-aminothiophenol has been studied. A series of new 2-substituted benzazoles has been synthesized containing arylsulfonyl(thio)propionic acid fragments.
Keywords:benzimidazole  benzoxazole  benzothiazole  imino ester hydrochlorides of carboxylic acids  nitriles  condensation
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