Enhanced photovoltaic performance of quasi-solid-state dye-sensitized solar cells via incorporating quaternized ammonium iodide-containing conjugated polymer into PEO gel electrolytes |
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Authors: | Rong-Ho Lee Tun-Fang Cheng Jhih-Wei Chang Jhu-Heng Ho |
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Institution: | (1) Department of Chemical Engineering, National Chung Hsing University, Taichung, Taiwan;(2) Department of Chemical and Materials Engineering, National Yunlin University of Science & Technology, Yunlin, Taiwan |
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Abstract: | In this study, a series of gel electrolytes prepared from blends of alternating conjugated polymer electrolytes (CPEs)/poly(ethylene
oxide) (PEO) were developed for use in quasi-solid-state dye-sensitized solar cells (DSSCs). The alternating CPEs poly(N-(3′-((N,N-dimethyl)-N-ethylammonium)propyl)-3,6-carbazole)-alt-(9,9-dioctyl-2,7-fluorene)]diiodide, poly(N-(3′-((N,N-dimethyl)-N-ethylammonium)propyl)-3,6-carbazole)-alt-(9,9-bis(2-(2-methoxyethoxy)ethyl)-2,7-fluorene)]diiodide (MPCFO-E), and poly(N-(3′-((N,N-dimethyl)-N-ethylammonium)propyl)-3,6-carbazole)-alt-(siloxane substituted-2,7-fluorene)]diiodide (MPCFS-E) were synthesized through copolymerization of carbazole units (featuring
quaternized ammonium iodide groups) and fluorene units featuring flexible side chains (9,9-dioctylfluorene, ethylene oxide-substituted
fluorene, and siloxane-substituted fluorene, respectively). The MPCFO-E/PEO-based and MPCFS-E/PEO-based DSSCs exhibited lower
electrochemical resistances, superior photovoltaic (PV) properties, and improved PV stabilities relative to those of the corresponding
PEO-based DSSC. Among the studied systems, the DSSC based on the MPCFO-E (0.5 wt.%)/PEO blend electrolyte exhibited the best
PV performance, with a short current density of 4.97 mA cm−2 and a photoenergy conversion efficiency of 1.17%. |
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