Iron‐Catalyzed Stereoselective Cross‐Coupling Reactions of Stereodefined Enol Carbamates with Grignard Reagents |
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| Authors: | Ana Cristina Parra Rivera Raymond Still Prof Doug E Frantz |
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| Institution: | Department of Chemistry, The University of Texas at San Antonio, San Antonio, TX, USA |
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| Abstract: | A practical and highly stereoselective iron‐catalyzed cross‐coupling reaction of stereodefined enol carbamates and Grignard reagents to yield tri‐ and tetrasubstituted acrylates is reported. A facile method for the stereoselective generation of these enol carbamates has also been developed. |
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| Keywords: | acrylates cross-coupling enol carbamates iron catalysis stereoselective synthesis |
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