Dithienophosphole‐Based Phosphinamides with Intriguing Self‐Assembly Behavior |
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Authors: | Zisu Wang Benjamin S Gelfand Prof?Dr Thomas Baumgartner |
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Institution: | 1. Department of Chemistry and Centre for Advanced Solar Materials, University of Calgary, Calgary, AB, Canada;2. http://www.ucalgary.ca/chem/pages/Baumgartner
0000-0001-8066-0559
Department of Chemistry and Centre for Advanced Solar Materials, University of Calgary, Calgary, AB, Canada |
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Abstract: | A new, highly adaptable type of phosphinamide‐based hydrogen bonding is representatively demonstrated in π‐conjugated phosphole materials. The rotational flexibility of these intermolecular P=O?H?N hydrogen bonds is demonstrated by X‐ray crystallography and variable‐concentration NMR spectroscopy. In addition to crystalline compounds, phosphinamide hydrogen bonding was successfully introduced into the self‐assembly of soft crystals, liquid crystals, and organogels, thus highlighting the high general value of this type of interaction for the formation of organic soft materials. |
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Keywords: | hydrogen bonds phosphinamides phosphorus heterocycles self-assembly soft materials |
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