| 含氮手性杯[4]芳烃对羧酸的手性识别 |
| |
| 引用本文： | 郑炎松,肖勤. 含氮手性杯[4]芳烃对羧酸的手性识别[J]. 中国化学, 2005, 23(10): 1289-1291. DOI: 10.1002/cjoc.200591289 |
| |
| 作者姓名： | 郑炎松 肖勤 |
| |
| 作者单位： | [1]Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, China |
| |
| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20072007）. |
| |
| 摘 要： | Chiral nitrogen-containing calix[4]arene was easily synthesized by the reaction of 25,27-di（2-bromoethoxy）- 26,28-dihydroxy-5,11,17,23-tetrakis（t-butyl）calix[4]arene with S-（-）-1-phenylethylamine in excellent yield, and showed good ability to recognize the enantiomers of mandelic acid and 2,3-dibenzoyltartaric acid. This finding has potential application to assay and separation of enantiomers of the carboxylic acids.
|
| 关 键 词： | 芳烃 手性化合物 含氮量 羧酸 |
| 收稿时间： | 2004-11-16 |
| 修稿时间： | 2004-11-162005-07-13 |
Chiral Recognition of Carboxylic Acids by Chiral Nitrogen Containing Calix[4]arene |
| |
| Zheng YanSong;Xiao Qin. Chiral Recognition of Carboxylic Acids by Chiral Nitrogen Containing Calix[4]arene[J]. Chinese Journal of Chemistry, 2005, 23(10): 1289-1291. DOI: 10.1002/cjoc.200591289 |
| |
| Authors: | Zheng YanSong Xiao Qin |
| |
| Abstract: | Chiral nitrogen‐containing calix[4]arene was easily synthesized by the reaction of 25,27‐di(2‐bromoethoxy)‐26,28‐dihydroxy‐5,11,17,23‐tetrakis(t‐butyl)calix[4]arene with S‐((?)‐1‐phenylethylamine in excellent yield, and showed good ability to recognize the enantiomers of mandelic acid and 2,3‐dibenzoyltartaric acid. This finding has potential application to assay and separation of enantiomers of the carboxylic acids. |
| |
| Keywords: | chiral nitrogen-containing calix[4]arene chiral recognition carboxylic acid. |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《中国化学》浏览原始摘要信息 |
|
点击此处可从《中国化学》下载全文 |
|
