| 甲基丙烯酸2-(N-吖啶酮基)乙酯的合成及其敏化的烯类单体光聚合 |
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| 引用本文： | 杜福胜,李福绵.甲基丙烯酸2-(N-吖啶酮基)乙酯的合成及其敏化的烯类单体光聚合[J].高分子学报,1992,0(6):752-757. |
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| 作者姓名： | 杜福胜 李福绵 |
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| 作者单位： | 北京大学化学系 10087l |
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| 摘 要： |
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| 关 键 词： | 光聚合 AEMA 丙烯腈 |
| 收稿时间： | 1992-03-10 |
SYNTHESIS OF 2-(N-ACRIDONO) ETHYL METHACRYLATE AND THE INITIATION FOR PHOTOPOLYMERIZATION OF VINYL MONOMERS |
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| DU Fu-sheng,LI Fu-mian.SYNTHESIS OF 2-(N-ACRIDONO) ETHYL METHACRYLATE AND THE INITIATION FOR PHOTOPOLYMERIZATION OF VINYL MONOMERS[J].Acta Polymerica Sinica,1992,0(6):752-757. |
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| Authors: | DU Fu-sheng LI Fu-mian |
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| Institution: | Department of Chemistry; Peking University; Beijing; Post cord: 100871 |
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| Abstract: | A novel acrylic monomer having acridonechromophore, 2-(N-acridonono)ethyl methacry-late (AEMA) was prepared from methacryloyl chloride and N-hydroxyethyl acridone (HEA), which was obtained by reaction of acridone with ethylene carbonate. Both the monomer and its polymer can initiate the photopolymerization of vinyl monomers, such as AN, MMA etc, but P(AEMA) has higher initiation ability than monomeric AEMA does. The effects of oxygen and aliphatic tertiary amine on the polymerization rate were also revealed. The UV-analysis indicates that AEMA not only initiates photopolymerization of vinyl monomers,but also enters into the polymer chains. |
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