Reaction d'un thiolate de molybdene sur l'hexafluorobutyne |
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| Authors: | F.Y. Petillon D.W.A. Sharp |
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| Affiliation: | 1. Laboratoire de chimie inorganique moléculaire de l''Université de Bretagne Occidentale, 6, Avenue Le Gorgeu, 29283 BREST-Cedex, France;2. Department of Chemistry, University of Glasgow, Glasgow G12 8QQ UK |
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| Abstract: | ![]()
Bis(methyl)disulphide and the organometallic compound {(Cp)Mo(CO)3}2 in low oxidation state under photolysis give especially with the hexa-fluorobut-2 yne a 18-electron olefin complexe {(Cp)Mo(CO)3(CF3C2CF3SCH3)}. The new compounds are reported and the reaction discussed. |
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