Perfluoralkyljod-verbindungen: das trifluormethyljod-bis-trifluoracetat CF3J(OCOCF3)2 |
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| Authors: | Dieter Naumann Jürgen Baumanns |
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| Institution: | Lehrstuhl für Anorganische Chemie, Universität Dortmund, 4600 Dortmund 50, Postfach 500500 Bundesrepublik Deutschland |
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| Abstract: | CF3I(OCOCF3)2 is formed from the reactions of CF3IF2 or CF3IO with trifluoroacetic anhydride at low temperature. During the reaction of CF3IF2 with (CF3CO)2O CF3IF(OCOCF3) is formed as an intermediate product. The preparation, the 19F-nmr spectra and the thermal decomposition are described. |
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