Chiral (6,3) Network Assembled by Lanthanide and Changeful Dihydroxyfumaric Acid |
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| Authors: | Manbo Zhang Jing Lü Ruixiang Hu |
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| Institution: | Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, Hunan 410081, China |
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| Abstract: | A series of chiral two‐dimensional lanthanide coordination polymers, Ln2(L)3(H2O)6]n·n/3H2O Ln=Nd ( 1a , 1b ), Sm ( 2 ), Eu ( 3 ), Tb ( 4 ), Dy (5 ), Ho ( 6 ), Er ( 7 ); H2L=2,2‐dihydroxylmalonic acid], have been hydrothermally synthesized by using dihydroxyfumaric acid as a source of polydentate O‐donor ligands. The luminescence behaviors of 3 and 4 have been investigated, and they exhibit strong red and green fluorescence in the visible region respectively. |
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| Keywords: | chiral coordination polymer lanthanide dihydroxyfumaric acid 2 2‐dihydroxylmalonate |
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