The electrochemistry of organotransition-metal complexes : II. Formation and reactivity of the radical cations [trans-Fe(CO3(PR3)2]+ and [Fe(CO)3 (Ph2 PCH2 CH2 PPh2)]+ |
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| Authors: | Neil G Connelly Karen R Somers |
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| Institution: | Department of Inorganic Chemistry, The University of Bristol, Bristol BS8 1TS Great Britain |
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| Abstract: | Fe(CO)3 L2] (L = PPh3, PPh2Me, P(OPh)3 or P(NMe2)3; L2 = Ph2 PCH2 CH2 PPh2+) undergo reversible one-electron oxidations to give the radical cations Fe(CO)3L2]+ which have been studied by IR and ESR spectroscopy. |
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| Keywords: | Author to whom correspondence should be addressed |
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