Fluorinated polysilanes. palladium-catalyzed disilane metathesis,double silylation of acetylenes,and the stereo chemical course |
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Authors: | Kohei Tamao Tamio Hayashi Makoto Kumada |
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Affiliation: | Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606 Japan |
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Abstract: | ![]() Fluorinated and angle-strained Si—Si compounds undergo palladium-catalyzed disilane metathesis and double silylation of acetylenes, the latter being stereospecific at silicon atoms. |
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Keywords: | To whom correspondence should be addressed |
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