Abstract: | ![]() Structural Chemistry of PbBr2·C4H10O3 (Diethyleneglycol) Crystals of PbBr2·C4H10O3 have been synthesized and structurally characterized by single‐crystal X‐ray diffraction. PbBr2·C4H10O3 crystallizes monoclinic in space group P21/n (No. 14) with a = 9.370(1)Å, b = 10.045(1)Å, c = 21.090(1)Å, β = 98.98(1)° and Z = 8. The compound contains compact Pb—Br groups, which build colums parallel to [0 1 0] direction by Hydrogen Bonding. |