Syntheses,structures and electrochemical properties of complexes of nickel(II) with triethylenetetramine and bidentate nitrogen donor co-ligands |
| |
| Authors: | Ram N. Patel Manoj K. Kesharwani Anurag Singh Dheerendra K. Patel Mukesh Choudhary |
| |
| Affiliation: | (1) Department of Chemistry, A.P.S. University, Rewa, 486 003, M.P, India |
| |
| Abstract: | Three new polyamine Ni(II) complexes, namely [Ni(trien)(phen)](BF4)2 1, [Ni(trien)(bipy)](ClO4)2 2 and [Ni(trien)(en)](ClO4)2 3 [trine = triethylenetetramine, phen = 1,10-phenanthroline, bipy = 2,2′-bipyridyl, en = ethylenediamine] have been synthesized and characterized by physico-chemical and spectroscopic methods. Complexes 1 and 2 crystallize in monoclinic space group P21/c, and possess a distorted octahedral geometry. Significant hydrogen bonding interactions are found in both complexes. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
