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A Novel Octahedral Hexasilver(I) Cluster: Ag[SSCN(n—C4H9)2]6
引用本文:章伟光 苏成勇 等. A Novel Octahedral Hexasilver(I) Cluster: Ag[SSCN(n—C4H9)2]6[J]. 中国化学, 2002, 20(5): 420-423. DOI: 10.1002/cjoc.20020200503
作者姓名:章伟光 苏成勇 等
作者单位:[1]DepartmentofChemistry,LanzhouUniversity,Lanzhou,Gansu730000,China;DepartmentofChemistry,SouthChinaNormalUniversity,Guangzhou,Guangdong510631,China [2]SchoolofChemistryandChemicalEngineer,LanzhouUniversity,Lanzhou,Gansu730000,China;DepartmentofChemistry,SouthChinaNormalUniversity,Guangzhou,Guangdong510631,China
摘    要:
The first crystal structural report of a AgDTC complex (DTC-dialkyldithiocarbamate,R=n-butyl)presented in this paper shows that it is a hexanuclear species.The structural arrangement for the DDP(dialkyldithiophosphate)ligands is different from that of Cu6(DDP)6,but is the same as that of Ag6-[SSP(O-i-Pr)2]6.

关 键 词:Ag[SSCN(n-C4H9)2]6 银配合物 晶体结构 二丁基二硫代氨基甲酸酯 X射体衍射

A Novel Octahedral Hexasilver(I) Cluster: Ag6[SSCN(n‐C4H9)2]6
Wei‐Guang Zhang,Yun Zhong,Min‐Yu Tan,Wei‐Sheng Liu,Cheng‐Yong Su. A Novel Octahedral Hexasilver(I) Cluster: Ag6[SSCN(n‐C4H9)2]6[J]. Chinese Journal of Chemistry, 2002, 20(5): 420-423. DOI: 10.1002/cjoc.20020200503
Authors:Wei‐Guang Zhang  Yun Zhong  Min‐Yu Tan  Wei‐Sheng Liu  Cheng‐Yong Su
Abstract:
The first crystal structural report of a AgDTC complex (DTC = dialkyldithiocarbamate, R = n‐butyl) presented in this paper shows that it is a hexanuclear species. The structural arrangement for the DDP (dialkyldithiophosphate) ligands is different from that of Cu6(DDP)6, but is the same as that of Ag6‐[SSP(O‐i‐Pr)2]6.
Keywords:X‐ray crystal structure  cluster  silver n‐dibutyldithiocarbamate complex
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