Catalytic decomposition of N2O on La2Cu0.5M0.5O4 (M=Co, Ni, Cu and Zn) |
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Authors: | U. Kameswari J. Christopher C. S. Swamy |
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Affiliation: | (1) Department of Chemistry, Indian Institute of Technology, 600 036 Madras, India |
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Abstract: | Decomposition of N2O has been studied over La2Cu0.5M0.5O4 (M=Co, Ni, Cu and Zn) between 380 and 485°C at 50 torr initial pressure of N2O to understand the mutual interaction of two different active metal ions of the same concentration and valence in deciding the physico-chemical and catalytic properties. A multicenter type of adsorption of N2O has been visualized and it is found that the rate is governed by the electronic factor.
         N2O                        La2Cu0,5M0,5O4 (M=Co, Ni, Cu Zn)                  380–485°C                 N2O,      50    .                                                                                                     ,                -                                        .                                         N2O.                                   .
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