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土壤中砷形态分析研究进展
引用本文:秦玉燕,王运儒,时鹏涛,杜国冬,蓝唯,农耀京. 土壤中砷形态分析研究进展[J]. 分析科学学报, 2017, 33(4). DOI: 10.13526/j.issn.1006-6144.2017.04.027
作者姓名:秦玉燕  王运儒  时鹏涛  杜国冬  蓝唯  农耀京
作者单位:广西壮族自治区亚热带作物研究所,广西南宁530001;农业部亚热带果品蔬菜质量监督检验测试中心,广西南宁530001
基金项目:广西壮族自治区公益性科研院所基本科研业务费专项资金
摘    要:本文评述了近年来国内外土壤中砷形态分析的主要研究方法,包括联用分析法、分级提取法和同步辐射X-射线线吸收光谱法。联用分析法包括气相色谱联用法、毛细管电泳联用法和高效液相色谱联用法。重点介绍了目前应用范围较广的高效液相色谱-等离子体质谱(HPLC-ICP-MS)联用法和高效液相色谱-氢化物发生-原子荧光光谱(HPLC-HG-AFS)联用法。同步辐射X-射线线吸收光谱法近几年发展迅速,是最具发展潜力的形态分析方法。

关 键 词:土壤    形态分析  研究进展

Research Progress of Arsenic Speciation Analysis in Soil
QIN Yu-yan,WANG Yun-ru,SHI Peng-tao,DU Guo-dong,LAN Wei,NONG Yao-jing. Research Progress of Arsenic Speciation Analysis in Soil[J]. Journal of Analytical Science, 2017, 33(4). DOI: 10.13526/j.issn.1006-6144.2017.04.027
Authors:QIN Yu-yan  WANG Yun-ru  SHI Peng-tao  DU Guo-dong  LAN Wei  NONG Yao-jing
Abstract:Arsenic contamination in soil has become a global environmental and health problem,and analysis in soil are the basis for environmental health risk assessment,arsenic pollution recognition and remediation.In this paper,main analytical techniques including hyphenated techniques,sequential extraction and synchrotron radiation X-ray adsorption spectroscopy for arsenic speciation in soil are reviewed.Hyphenated techniques of gas chromatography,capillary electrophoresis and high-performance liquid chromatography were described and HPLC-ICP-MS and HPLC-HG-AFS have a wide application potential in arsenic speciation analysis in soils.In recent years,synchrotron radiation x-ray adsorption spectroscopy is developing rapidly,and has been proved to be the most promising technique for arsenic speciation in soil.
Keywords:Soil  Arsenic  Speciation analysis  Research progress
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