Volumetric
properties of 1-iodoperfluorohexane+<Emphasis Type="Italic">n</Emphasis>-octane
binary system at several temperatures |
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Authors: | L Lugo M J P Comuñas E R López J Fernández |
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Institution: | (1) Laboratorio de Propiedades Termofísicas, Dpto. de Física Aplicada, Facultade de Física, Universidade de Santiago de Compostela, Santiago de Compostela, Spain, 5782 |
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Abstract: | New densities are reported over the whole composition range for 1-iodoperfluorohexane+n-octane system at temperatures from 288.15 to 308.15
K at atmospheric pressure. These data have been used to compute the excess
molar volumes, V
m
E.
Large positive V
m
E
values have been obtained over the entire range of composition, which increases
when the temperature rises. The experimental data were used to calculate the
isobaric thermal expansivity, and the quantities (∂V
m
E/∂T)p and (∂H
m
E/∂p)T. Furthermore,
the results have been used to investigate the volumetric prediction ability
of the equations of state Soave–Redlich–Kwong, Peng–Robinson,
Patel–Teja and Soave–Redlich–Kwong with volume translation. |
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Keywords: | density correlation equation of state excess molar volume FIC 1-iodoperfluorohexane |
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