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Volumetric properties of 1-iodoperfluorohexane+<Emphasis Type="Italic">n</Emphasis>-octane binary system at several temperatures
Authors:L Lugo  M J P Comuñas  E R López  J Fernández
Institution:(1) Laboratorio de Propiedades Termofísicas, Dpto. de Física Aplicada, Facultade de Física, Universidade de Santiago de Compostela, Santiago de Compostela, Spain, 5782
Abstract:New densities are reported over the whole composition range for 1-iodoperfluorohexane+n-octane system at temperatures from 288.15 to 308.15 K at atmospheric pressure. These data have been used to compute the excess molar volumes, V m E. Large positive V m E values have been obtained over the entire range of composition, which increases when the temperature rises. The experimental data were used to calculate the isobaric thermal expansivity, and the quantities (∂V m E/∂T)p and (∂H m E/∂p)T. Furthermore, the results have been used to investigate the volumetric prediction ability of the equations of state Soave–Redlich–Kwong, Peng–Robinson, Patel–Teja and Soave–Redlich–Kwong with volume translation.
Keywords:density correlation  equation of state  excess molar volume  FIC  1-iodoperfluorohexane
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