New sesquiterpenes from Ferula ferulaeoides (Steud.) Korovin. VI. Isolation and identification of three new dihydrofuro[2,3-b]chromones |
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Authors: | Nagatsu Akito Isaka Kimio Kojima Keisuke Ondognii Purev Zevgeegiin Oyun Gombosurengyin Purevsuren Davgiin Khishgee Irfan Baig Iqubal Choudhary Muhammad Ogihara Yukio |
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Institution: | Graduate School of Pharmaceutical Sciences, Nagoya City University, Nagoya, Japan. |
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Abstract: | Three novel 2-prenyl-dihydrofurochromone-type sesquiterpenoid derivatives, 2,3-dihydro-7-hydroxy-2S*,3R*-dimethyl-2-4,8-dimethyl-3(E),7-nonadienyl]-furo2,3-b]chromone, 2,3-dihydro-7-hydroxy-2S*,3R*-dimethyl-2-4-methyl-5-(4-methyl-2-furyl)-3(E),7-pentenyl]-furo2,3-b]chromone, and 2,3-dihydro-7-hydroxy-2R*,3R*-dimethyl-2-4-methyl-5-(4-methyl-2-furyl)-3(E),7-pentenyl]-furo2,3-b]chromone, were isolated from the roots of Ferula ferulaeoides. The structures were established by comprehensive spectral analysis. The biosynthetic pathway leading to these 2-prenyl-dihydrofurochromone-type sesquiterpenoids is proposed based on their structures. |
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