| 三环己基锡芳氧乙酸盐的合成及其结构表征 |
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| 引用本文： | 谢庆兰,郑健禺.三环己基锡芳氧乙酸盐的合成及其结构表征[J].有机化学,1991,11(1):82-87. |
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| 作者姓名： | 谢庆兰 郑健禺 |
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| 作者单位： | 南开大学元素有机化学研究所，南开大学元素有机化学研究所 天津，300071，天津，300071 |
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| 摘 要： | 三环己基锡衍生物(Cy_3SnX,Cy=环己基,X=配体或取代基)是一类具有较强生物活性的有机锡化合物,它们广泛用作杀螨剂,杀菌剂和海洋防污剂。有关三环己基锡芳氧乙酸盐的合成至今报道很少。Bubblitz 合成了两个三环已基锡芳氧乙酸盐,此后,Matsuda 等人制备了三环已基锡-2,4-二氯苯氧乙酸盐,它们都具有良好的杀螨、杀菌活性,后者还可应用于海洋
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| 关 键 词： | 三环己基锡 芳氧乙酸盐 合成 杀螨活性 除草活性 |
Synthesis and Structure of Tricyclohexylstannane Aromatoxyacetates |
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| XIE Qing-Lan ZHENG Jian-Yu.Synthesis and Structure of Tricyclohexylstannane Aromatoxyacetates[J].Chinese Journal of Organic Chemistry,1991,11(1):82-87. |
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| Authors: | XIE Qing-Lan ZHENG Jian-Yu |
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| Abstract: | Fourteen tricyclohexylstannane aromatoxyacetates were synthesized by reaction oftricyclohexylstannane hydroxide and aromatoxyacetic acids.All of these compounds are aca-ricidal activity and herbicidal activity.The IR,~1H NMR and ~(13)C NMR of these compoundshad been studied.All of these results concluded that the structure of tricyclohexylstannanearomatoxyacetates consist of a distored tetrahedron containing four-coordinated tin atom. |
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| Keywords: | tricyclohexylstannane aromatoxyacetate synthesis acaricidal activity herbicidal activity |
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