| Synthesis and Crystal Structure of Potassium Triethylenetetraaminehexaacetatodi [Oxo-vanadium(Ⅳ)] Hexahydrate, K_2[V_2O_2(ttha)]·6(H_2O) |
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| 作者姓名： | 燕亚琪 谢兆雄 |
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| 作者单位： | JIANG Ya-Qia XIE Zhao-Xiongb a (Department of Chemistry,Xiamen University,Xiamen 361005,China) b (State Key Laboratory for Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005,China) |
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| 基金项目： | the National Natural Science Foundation of China (20173046) |
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| 摘 要： | 1 INTRODUCTION Interest in vanadium in the physiology and biochemistry has promoted enormously in recent years. Vanadium is known to exist in alternative nitrogenase metalloenzyme systems fixing nitrogen. It is also found to participate in biological processes exhibiting mitogenic behavior and enzyme inhi- bition[1]. Up to date, several crystal structures have been reported about vanadium with carboxylic or polycarboxylic acid[2, 3]. However, very few struc- tures of vanadium complexes …
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