Syntheses,characterizations and properties of boronoalkylalkoxycalix[4]arenes |
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| Institution: | 1. Cellular and Molecular Biotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 6, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8566, Japan;2. Department of Surgery, Clinical Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki, 305-8575, Japan;1. Laboratory of Biosensing Technology, School of Life Sciences, Shanghai University, Shanghai 200444, PR China;2. Shanghai Key Laboratory of Bio-Energy Crop, School of Life Sciences, Shanghai University, Shanghai 200444, PR China;3. State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, PR China;4. Institute of General Education, Pusan National University, Busan 609-735, Republic of Korea;5. Department of Oncology, The Second Affiliated Hospital of Nanjing Medical University, Nanjing 210011, PR China;1. CERZOS-CONICET, CCT Bahía Blanca, Camino La Carrindanga km 7, B8000FWB, Bahía Blanca, Argentina;2. Departament of Biochemistry and Molecular Biology-A, Faculty of Biology, University of Murcia, Campus Espinardo, 30071, Murcia, Spain;1. State Key Laboratory of Biotherapy and Cancer Center, West China Hospital, Sichuan University, Chengdu, Sichuan 610041, China;2. Key Laboratory of Drug Targeting and Drug Delivery System of Ministry of Education, West China School of Pharmacy, Sichuan University, Chengdu, Sichuan 610041, China |
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| Abstract: | Some new calixarenes bearing boronic acid moieties, boronoalkylalkoxycalix4]arenes, were synthesized by allylation, Claisen's rearrangement, alkylation, hydroboration and hydrolysis from 25,26,27,28-tetrahydroxycalix4]arene and their structures were identified by elemental analysis, IR, 1H NMR, 13C NMR, 11B NMR, MS and UV spectra. The UV data showed that tetraalkoxycalix4]arene tetraalkyltriboronic acid could coordinate significantly with carbohydrates. |
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