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Bright white light through up-conversion of a single NIR source from sol-gel-derived thin film made with Ln3+-doped LaF3 nanoparticles
Authors:Sivakumar Sri  van Veggel Frank C J M  Raudsepp Mati
Institution:Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, British Columbia, Canada V8W 3V6.
Abstract:White light was generated from a single silica thin film made with Yb0.75La0.2Eu0.05F3, La0.45Yb0.5Er0.05F3, and La0.75Yb0.2Tm0.05F3 nanoparticles by exciting with a single source near-infrared light (980 nm CW diode laser). Eu3+ and Tm3+ ions are responsible for red and blue emission, respectively. Er3+ ion is responsible for green as well as red emission. The Commission Internationale de l'Eclairage (CIE) coordinates of the resulting light were easily adjusted by controlling the concentration of Ln3+ (Eu3+, Er3+, Tm3+) ions in the nanoparticles as well as the concentration of Ln3+-doped nanoparticles in the sol-gel thin layer.
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