A novel [Cu II 4] cluster from the assembly of two [Cu II 2L]+ units by a central mu4-1,1,2,2 perchlorate ligand |
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| Authors: | Paital Alok Ranjan Bertolasi Valerio Aromí Guillem Ribas-Ariño Jordi Ray Debashis |
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| Institution: | Department of Chemistry, Indian Institute of Technology, Kharagpur, 721 302, India. |
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| Abstract: | A perchlorate ligand in the rare mu4-1,1,2,2 binding mode is seen for the first time as the sole support for the assembly of two cationic Cu II 2L]+ fragments (H3L = a dinucleating ligand) in the formation of a magnetically-exchanged tetranuclear cluster. |
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