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Vapor pressure and enthalpy of vaporization of linear aliphatic alkanediamines
Authors:Vasiliy A. Pozdeev  Sergey P. Verevkin
Affiliation:aDepartment of Physical Chemistry, University of Rostock, Dr-Lorenz-Weg 1, D-18059 Rostock, Germany;bFaculty of Interdisciplinary Research, Department “Science and Technology of Life, Light and Matter”, University of Rostock, Rostock, Germany
Abstract:
Vapor pressures and the molar enthalpies of vaporization of the linear aliphatic alkanediamines H2N–(CH2)n–NH2 with n = (3 to 12) have been determined using the transpiration method. A linear correlation of enthalpies of vaporization (at T = 298.15 K) of the alkanediamines with the number n and with the Kovat’s indices has been found, proving the internal consistency of the measured data.
Keywords:Vapor pressure   Enthalpy of vaporization   Transpiration method   Alkanediamines   Kovats index
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