SEARCH FOR SINGLET OXYGEN LUMINESCENCE IN THE DISPROPORTIONATION OF HO2/O2 |
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| Authors: | Ravindra L. Arudi Benon H. J. Bielski Augustine O. Allen |
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| Affiliation: | Department of Chemistry, Brookhaven National Laboratory, Upton, NY 11973, USA |
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| Abstract: | Abstract— During the reaction HO2+ HO2 (or O2-) = H2O2+ O2 in aqueous solution, no luminescence in the region 620–720 nm, expected if the product O2 were formed in a singlet state, could be detected. If any singlet O2 is formed, its yield must be less than 10%. Faint luminescence, sometimes found at shorter wavelengths, was shown to arise from reaction of HO2 with impurities in the reagents present. |
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