Oxidative coupling of 5-membered heterocycles catalyzed by a Pd(II)-heteropolyacid system in dimethylformamide |
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| Authors: | V. E. Tarabanko I. V. Kozhevnikov K. I. Matveev |
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| Affiliation: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | ![]()
Oxidative coupling of thiophene and 2-methylfuran to the corresponding dihetaryls in DMFA medium occurs in the presence of the homogeneous catalytic system Pd(II)-molybdovanodophosphoric heteropolyacid (HPA). The data obtained show that HPA may act as a reversible oxidant in polar aprotic media.
         ,           Pd(II)-          2-   .   ,  .
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